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Whatever you do don't ASK a woman for her number.
NEVER.
By you 'asking' it suggests that you assume she may say "no".
If you are a man who has a lot to offer a woman, then why would you ever assume that she would say "no"?
When you have doubt, it comes across in your language and this puts doubt in a woman's mind.
In such a case, she would then more than likely hesitate, because she would be thinking; "should I really give this guy my number?"
Women want certainty.
She will look for certainty in you and she will look for it in your language. If you are not sure, how can you then expect her to be?
So never ask a woman for her number, command her instead. This is not the same as being controlling or dominating.
If you cannot command, then at the very least suggest and give her a reason to give it to you.
Don't just say "give me your number" in a forceful way. Instead say it with confidence and with certainty that she will give it to you, ...